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When steam distillation is used in the manufacture and extraction of essential oils, the botanical material is placed in a still and steam is forced over the material.

The hot steam helps to release the aromatic molecules from the plant material since the steam forces open the pockets in which the oils are kept in the plant material. The molecules of these volatile oils then escape from the plant material and evaporate into the steam.
The temperature of the steam needs to be carefully controlled - just enough to force the plant material to let go of the essential oil, yet not too hot as to burn the plant material or the essential oil.
The steam which then contains the essential oil, is passed through a cooling system to condense the steam, which forms a liquid from which the essential oil and water is then separated.
The steam is produced at greater pressure than the atmosphere and therefore boils at above 100 degrees Celsius which facilitates the removal of the essential oil from the plant material at a faster rate and in so doing prevents damage to the oil.
Some oils, like Lavender is heat sensitive (thermolabile) and with this extraction method, the oil is not damaged and ingredients like linalyl acetate will not decompose to linalool and acetic acid.
To view further information on extraction methods in essential oil manufacture, please visit the following links
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